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Structure and Bonding Atomic structure of carbon
Covalent bonding and hybridization. sp Hybridization. sp Hybridization. sp Hybridization Bonds and hybridized centers Alkanes and CycloalkanesDefinition Drawing structures Nomenclature Functional GroupsRecognition of functional groups Aliphatic and aromatic functional groups Intermolecular bonding Properties and reactions Nomenclature of compounds with functional groups Primary, secondary, tertiary and quaternary nomenclature StereochemistryConstitutional isomers Configurational isomers - alkenes and cycloalkanes Configurational isomers - optical isomers Conformational isomers Nucleophiles and ElectrophilesDefinition Charged species Neutral inorganic species Organic structures Reactions and Mechanisms Reactions Mechanisms Acid-base Reactions Bronsted-Lowry acids and bases Acid strength Base strength Lewis acids and bases Enolates Alkenes and Alkynes Preparation Properties Electrophilic addition to symmetrical alkenes Electrophilic addition to unsymmetrical alkenes Carbocation stabilization Reduction and oxidation of alkenes Hydroboration of alkenes Electrophilic additions to alkynes Reduction of alkynes Alkylation of terminal alkynes Conjugated dienes Aromatic Chemistry Aromaticity Preparation and properties Electrophilic substitutions of benzene Synthesis of mono-substituted benzenes Electrophilic substitutions of mono-substituted aromatic rings Synthesis of di- and tri-substituted benzenes Oxidation and reduction Aldehydes and Ketones Preparation Properties Nucleophilic addition Nucleophilic addition - charged nucleophiles Electronic and steric effects Nucleophilic addition - nitrogen nucleophiles Nucleophilic addition - oxygen and sulfur nucleophiles Reactions of enolate ions. a-Halogenation Reduction and oxidation Alpha, -Unsaturated aldehydes and ketones Carboxylic Acids and Carboxylic Acid Derivatives Structure and properties Nucleophilic substitution Reactivity Preparations of carboxylic acids Preparations of carboxylic acid derivatives Reactions Enolate reactions Alkyl Halides Preparation and physical properties Nucleophilic substitution Factors affecting SN2 vs. SN1 reactions. Elimination Elimination versus substitution Reactions of alkyl halides Organometallic reactions Spectroscopic analysis Alcohols, Phenols, and Thiols Preparation of alcohols Preparation of phenols Properties of alcohols and phenols Reactions of alcohols Reactions of phenols Chemistry of thiols Ethers, Epoxides and Thioethers Preparation Properties Reactions Amines and Nitriles Preparation of amines Properties of amines Reactions of amines Chemistry of nitriles Spectroscopic analysis Organic Spectroscopy and Analysis Spectroscopy Visible and ultra violet spectroscopy Infra-red spectroscopy Proton nuclear magnetic resonance spectroscopy C nuclear magnetic resonance spectroscopy Mass spectroscopy |