1. 서론
[연습문제]
1. 열역학 제1, 2, 3 법칙
[연습문제]
Ⅲ. 상태, 상태변수 그리고 프로세스
[연습문제]
IV. 이상기체의 거동
IV-1 Boyle-Charles Gas Law
IV-2 Van der Waals Equation
IV-3 Internal Energies of Ideal Gas and Real Gas
[연습문제]
V. 상태 변화 과정과 열 용량
V-1 Processes of Ideal Gas
(1) 등체적과정 (Constant Volume Process)
(2) 등압과정 (Constant Pressure Process)
(3) 단열과정 (Adiabatic Process)
(4) 등온과정 (Isothermal Process)
V-2 Heat Capacity
V-3 Enthalpy, H
V-4 Temperature Change during an Adiabatic Process
[연습문제]
VI. 엔트로피의 통계역학적 해석
VI-1 Definition of Entropy S
VI-2 Statistical Interpretation of Entropy
VI-3 Thermal Entropy and Configurational Entropy
VI-4 Boltzmann Distribution Function
VI-5 Proof of InΩ being proportional to Clausius Entropy S
[연습문제]
VII. 가역과정과 비가역과정
VII-1 Irreversible Process
VII-2 Entropy of Irreversible Processes
[연습문제]
VIII. 보조함수
VIII-1 Geometric Relations
VIII-2 Auxiliary Functions
(1) Enthalpy
(2) Helmholtz Free Energy
(3) Gibbs Free Energy
VIII-3 Differentials of Auxiliary Functions
VIII-4 Maxwell Relations
VIII-5 Applications of Maxwell Relation using Experimentally determined Parameters
[연습문제]
IX. 엔탈피와 엔트로피 함수 그리고 Gibbs 자유에너지
IX-1 Enthalpy as a function of Temperature under a constant Pressure
IX-2 Entropy as a function of Temperature under a constant Pressure
IX-3 Gibbs Free Energy as a function of Temperature under a constant Pressure.
IX-4 Phase Diagram determined from Gibbs Free Energy Change with Temperature and Pressure
IX-5 Clapeyron Equation
IX-6 Clausius-Clapeyron Equation
[연습문제]
X. 실제기체의 거동
X-1 Temperature Variation by Heat Transfer under constant Pressure
X-2 Pressure Variation by Work Transfer under constant Temperature
X-3 Van der Waals Gas Model describing Real Gas Behavior
[연습문제]
XI. 혼합 기체의 거동
XI-1 Gibbs Free Energy Variation with Pressure under constant Temperature
XI-2 Mixture of Ideal Gases
XI-3 Partial Molar Quantities and their Physical Meanings
XI-4 Chemical Potential as a Partial Molar Quantities
XI-5 Equilibrium Vapor Pressure of a Component in Condensed Solutions
XI-6 Activity and Activity Coefficient
XI-7 Raoult's Law and Henry's Law
XI-8 Chemical Potential and Activity
[연습문제]
XII. 화학반응 평형
XII-1 Reactions involving Gases
XII-2 Effect of Temperature on Chemical Reaction Equilibrium
XII-3 Reference Pressure and Effect of Total Pressure on Chemical Reactions
XII-4 Reactions involving Pure Condensed Phases and a Gaseous Phase
(1) CO/CO2 비율 조절을 이용한 산소분압 조절
(2) H2/H2O 비율 조절을 이용한 산소분압 조절
XII-5 Reactions involving Condensed Solution Phases and a Gaseous Phase
[연습문제]
XIII. 상태도
XIII-1 Free Energy Change as a Solute dissolving into a Matrix
XIII-2 Gibbs Free Energy of a Binary System
XIII-3 Ideal Solution
XIII-4 Development of Phase Diagrams
XIII-5 Development of Eutectic Phase Diagrams
XIII-6 Development of Other Phase Diagrams
[연습문제]
XIV. 용액모델
XIV-1 Non-ideal Mixing
XIV-2 Regular Solution Model
[연습문제]
XV. 전기화학 [중급]
XV-1 lonization Energy of an Element
XV-2 Equilibrium in Two Phase Systems involving an Electrolyte
XV-3 Equilibrium in an Electrochemical Cell
XV-4 Standard Hydrogen Electrode
XV-5 Pourbaix Diagram
(1) The Stability of Water
(2) Pourbaix Diagram for Copper
[연습문제]
XVI. 우세 영역도 [중급] (Predominance Area Diagram)
XVI-1 Reactions of a Metal with a Single Gas Component
XVI-2 Reactions of a Metal with Two Gas Components
[연습문제]
XVII. 계면 열역학 [중급]
XVII-1 Geometry of Surfaces
XVII-2 Conditions for Equilibrium in Systems with Curved Interfaces
XVII-3 Equilibrium Conditions in Unary Systems with Curved Boundaries
XVII-4 Chemical Potential of Atoms on Curved Surfaces
[연습문제]
XVIII. 결정결함 (Defects in Crystals) [중급]
XVIII-1 Point Defects in Elemental Crystals
XVIII-2 Conditions for Equilibrium in a Crystal with Vacancies
XVIII-3 Equilibrium Concentration of Vacancies in a Crystal
XVIII-4 Point Defects in Stoichiometric Compound Crystals
(1) Frenkel Defects
(2) Schottky Defects.
(3) Defect Association
(4) Extrinsic Point Defects in Stoichiometric Compound Crystals
XVIII-5 Point Defects in Non-stoichiometric Compound Crystals
(1) 산소결핍형 산화물
(2) 산소과잉형 산화물
(3) Brouwer Diagram
(4) Extrinsic Point Defects in Non-stoichiometric Compound Crystals
[연습문제]
XIX. 자유에너지의 의미 [중급]
XIX-1 Euler Equation
XIX-2 Legendre Transformation
XIX-3 Free Energy Functions
XIX-4 Equilibrium Condition
[연습문제]
XX. 희박용액 (Dilute Solution) [중급]
XX-1 Activities in Dilute Solutions
XX-2 Transformation of Standard States
XX-3 Measurements of Activity
[연습문제]
XXI. 용액의 기준상태 [중급]
XXI-1 Standard State of Components in Solutions
[연습문제]
[주요 용어 정리]
부록
A. 주관식 문제.
B. 연습문제 [정량적 문제] 풀이
찾아보기 (Index)